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Imidazole-functionalized nitrogen-rich Mg-Al-CO3 layered double hydroxide for developing highly crosslinkable epoxy with high thermal and mechanical properties

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Version 2 2024-06-12, 06:24
Version 1 2024-01-10, 13:18
journal contribution
revised on 2024-06-12, 06:24 and posted on 2024-06-12, 06:24 authored by Farzad Seidi, Maryam Jouyandeh, Seyed Mohammad Reza Paran, Amin Esmaeili, Zohre Karami, Sébastien Livi, Sajjad Habibzadeh, Henri Vahabi, Mohammad Reza Ganjali, Mohammad Reza Saeb

Ionic liquid-based N-octadecyl-N'-octadecyl imidazolium iodide functionalized layered double hydroxide (LDH-IM) was synthesized for manufacturing high-performance epoxy nanocomposites. Nonisothermal differential scanning calorimetry (DSC) was performed to study cure kinetics of epoxy reinforced قث with LDH and LDH-IM. Incorporation of Mg-Al-CO3 LDH into epoxy hindered the curing reaction, as detected by dimensionless Cure Index (CI). By contrast, epoxy/LDH-IM cured Good and Excellent due to imidazolium ionic liquid. Higher activation energy for completely cured epoxy/LDH-IM nanocomposite was obtained compared to epoxy and epoxy/LDH nanocomposites. The curing reaction rate was obtained by calculation of the orders of instantaneous autocatalytic and non-catalytic reactions, and optimal kinetic parameters based on isoconversional methods were in good agreement with experimental cure reaction rates. Lower value of Tg for epoxy/LDH nanocomposite compared to the neat epoxy signified weak interactions between Mg-Al-CO3-LDH and epoxy matrix, while a higher Tg was obtained for epoxy/LDH-IM. Network degradation kinetics of the samples was also investigated. The higher decomposition activation energy for epoxy/LDH-IM approved strong interfacial adhesion in the assigned system. The highly reactive nature of the developed LDH-IM gives reason for its usage for developing highly curable epoxy with high thermal and mechanical properties.

Other Information

Published in: Colloids and Surfaces A: Physicochemical and Engineering Aspects
License: https://creativecommons.org/licenses/by/4.0/
See article on publisher's website: https://dx.doi.org/10.1016/j.colsurfa.2020.125826


The University of Doha for Science and Technology replaced the now-former College of the North Atlantic-Qatar after an Amiri decision in 2022. UDST has become and first national applied University in Qatar; it is also second national University in the country.

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Language

  • English

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Elsevier

Publication Year

  • 2021

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This Item is licensed under the Creative Commons Attribution 4.0 International License.

Institution affiliated with

  • University of Doha for Science and Technology
  • College of Engineering and Technology - UDST
  • College of the North Atlantic - Qatar (-2022)
  • School of Engineering Technology and Industrial Trades - CNA-Q (-2022)

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