A fouling-resistant mixed-matrix nanofiltration membrane based on covalently cross-linked Ti₃C₂TX (MXene)/cellulose acetate

A new fouling-resistant mixed-matrix nanofiltration membrane based on a covalently cross-linked Ti₃C₂T_X (MXene)/cellulose acetate (MXene@CA) composite was fabricated by phase inversion followed by formaldehyde cross-linking. The physicochemical properties of the prepared MXene@CA composite membranes were studied by field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), and water contact angle techniques. The performance of the prepared membranes was evaluated with respect to the water flux, bacterial growth inhibition, and rejection properties. The 10%MXene@CA (10:90 wt % of MXene:CA) composite membrane shows high pure water flux of ~256.85 L m⁻² h⁻¹ bar⁻¹, 123.28% water uptake, and 69.7% porosity. The 10%MXene@CA membrane, exhibited more than 92% and 98% rejection of rhodamine B (RhB) and methyl green (MG), respectively. Furthermore, 10%MXene@CA membrane exhibited more than 98% and 96% growth inhibition for E. coli and B. subtilis, respectively. Also, the optimal membrane showed a significantly improved hydrophilicity (water contact angle = 60.8°), which has favored good antifouling properties. The reported nanofiltration membrane, especially 10%MXene@CA, can be suggested for water purification and biomedical applications.

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Published in: Journal of Membrane Science
License: http://creativecommons.org/licenses/by/4.0/
See article on publisher's website: https://dx.doi.org/10.1016/j.memsci.2020.118139